縮寫代號表(STUVZ)
|
s |
Singlet or second |
|
SATE |
S-Acetylthioethyl |
|
Scm |
S-Carboxymethylsulfenyl |
|
ScmCl |
Methoxycarbonylsulfenyl chloride |
|
SEE |
1-[2-(Trimethylsilyl)ethoxy]ethyl |
|
SEM |
Trimethylsilylmeyhoxyethyl |
|
SES |
b-Trimethylsilylethanesulfonyl |
SET |
Single electron transfer |
Sisyl |
Tris(trimethylsilyl)silyl |
SMEAH |
Sodium bis(2-methoxyethoxy)aluminum hydride |
|
SMOM |
(Phenyldimethylsilyl)methoxymethyl |
|
SN1 |
Unimolecular nucleophilic substitution |
|
SN2 |
Bimolecular nucleophilic substitution |
|
SN’ |
Nucleophilic substitution with allylic rearrangement |
Snm |
S-(N’-Methyl-N’-phenylcarbamoyl)sulfenyl |
|
STABASE |
1,1,4,4-Tetramethyldisilyl azacyclopentane |
|
Su |
Succinimidyl |
|
t |
Triplet |
|
Tacm |
Trimethylacetamidomethyl |
|
TAS-F |
Tris(dimethylamino)sulfonium difluorotrimethylsilicate |
|
TBAF |
Tetrabutylammonium fluoride |
|
TBAI |
Tetrabutylammonium iodide |
|
TBDMS/TBS |
t-Butyldimethylsilyl |
|
TBDPS |
t-Butyldiphenylsilyl |
|
TBDS |
Tetra-t-butoxydisiloxane-1,3-diylidene |
|
Tbf-DMTr |
4-(17-Tetrabenzo[a,c,g,i]fluorenylmethyl-4’,4”-dimethoxytrityl |
|
Tbfmoc |
17-Tetrabenzo[a,c,g,i]fluorenylmethoxycarbonyl |
|
TBHP |
t-Butyl hydroperoxide |
|
TBMPS |
t-Butylmethoxyphenylsilyl |
|
TBS |
Tributylsilane |
|
TBS/TBDMS |
t-Butyldimethylsilyl |
|
TBTr |
4,4’-4”-Tris(benzyloxy)triphenylmethyl |
|
TCB |
2,2,2-Trichloro-1,1-dimethylethyl |
|
TcBoc |
1,1-Dimethyl-2,2,2-trichloroethoxycarbonyl |
|
TCNE |
Tetracyanoethylene |
|
TCNQ |
7,7,8,8-Tetracyanoquinodimethane |
|
TCP |
N-Tetrachlorophthalimido |
|
Tcroc |
2-(Trifluoromethyl)-6-chromonylmethylene carbonyl |
|
Tcrom |
2-(Trifluoromethyl)-6-chromonylmethylene |
|
TDE |
(2,2,2-Trifluoro-1,1-diphenyl)ethyl |
|
TDS |
Thexyldimethylsilyl |
|
TEA |
Triethylamine |
|
TEAB |
Tetraethylammonium bromide |
|
TEBA |
Benzyltriethylammonium chloride |
|
TEBAC |
Benzyltriethylammonium chloride |
|
TED |
Triethylene diamine |
|
Teoc |
2-(Trimethylsilyl)ethoxycarbonyl |
|
TES |
Triethylsilyl |
|
TESH |
Triethylsilane |
|
Tf |
Trifluoromethanesulfonyl |
|
TFA |
Trifluoroacetic acid |
|
TFAA |
Trifluoroacetic acid |
|
Tfav |
4,4,4-Trifluoro-3-oxo-1-butenyl |
|
TFMSA |
Trifluoromethanesulfonic acid |
|
TfOH |
Trifluoromethanesulfonic acid |
|
Thexyl |
2,3-Dimethyl-2-butyl |
|
THF |
Tetrahydrofuran |
|
THP |
Tetrahydropyran |
|
TIBS |
Triisobutylsilyl |
|
TIPDS |
1,3-(1,13,3-Tetraisopropyldisiloxanyllidene) |
|
TIPS |
Triisopropylsilyl |
|
TLTr |
4,4’,4”-Tris(levulinoxy)triphenylmethyl |
|
Tmb |
2,4,6-Trimethylbenzyl |
|
Tmob |
Trimethoxybenzyl |
|
TMEDA |
N,N,N’,N’-Tetramethylethylene diamine |
|
TMG |
1,1,3,3-Tetramethylguanidine |
|
TMOF |
Trimethyl orthoformate |
|
TMP |
2,2,6,6-Tetramethyl piperidine |
|
TMPM |
Trimethoxyphenylmethyl |
|
TMS |
Trimethylsilyl or Tetramethylsilane |
|
TMSE/TSE |
2-(Trimethylsilyl)ethyl |
|
TMSEC |
2-(Trimethylsilyl)ethoxycarbonyl |
|
TMSP |
2-Trimethylsilylprop４-2-enyl |
|
TMTr |
Tri(p-methoxyphenyl)methyl |
|
TOCSY |
Totally Correlated SpectroscopY |
|
TOF |
Time of flight |
|
Tol |
Tolyl |
|
Torr |
1 mmHg |
|
Tos/Ts |
p-Toluenesulfonyl |
|
TPAP |
Tetrapropylammonium perruthanate (Pr)4NRuO4 |
|
TPP |
Tetraphenylporphine |
|
TPPTS |
Sulfonated triphenylphosphine |
|
TPS |
Triisopropylbenzenesulfonyl |
|
TPS |
Triphenylsilyl |
|
tR |
Retention time |
|
TPTE |
2-(4-Triphenylmethylthio)ethyl |
|
Tr |
Trityl (triphenylmethyl) |
|
Tr+BF4- or Ph3C+BF4- |
Triphenylcarbenium tetrafluoroborate |
|
Triton B |
Benzyltrimethylammonium hydroxide |
|
Tritylone |
9-(9-Phenyl-10-oxo)anthryl |
|
Troc |
2,2,2-Trichloroethoxycarbonyl |
|
TrS-Bu4N+ |
Tetrabutylammonium triphenylmethanethiolate |
|
Ts/Tos |
p-Toluenesulfonyl or Tosyl |
|
TS |
Transition state |
|
TSA |
p-Toluenesulfonic acid |
|
Tse |
2-(p-Toluenesulfonyl)ethyl |
|
TsOH |
p-Toluenesulfonic acid |
|
TyrOH |
Tyrosine |
|
UV |
Ultraviolet |
|
Voc |
Vinyloxycarbonyl |
|
Z or Cbz |
Benzyloxycarbonyl |
